ic035451+_si_001.cif (161.24 kB)
Functionalized Thiosemicarbazone Clusters of Copper(I) and Silver(I)
dataset
posted on 2004-07-12, 00:00 authored by Laura J. Ashfield, Andrew R. Cowley, Jonathan R. Dilworth, Paul S. DonnellyReaction of [Cu(MeCN)4]+ with thiosemicarbazones bearing groups
such as phenol, pyridine, or ferrocene gives tetranuclear or
hexanuclear clusters with functional substituents; analogous air
stable fluorescent clusters can also be prepared with Ag(I).
