American Chemical Society
ic035451+_si_001.cif (161.24 kB)

Functionalized Thiosemicarbazone Clusters of Copper(I) and Silver(I)

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posted on 2004-07-12, 00:00 authored by Laura J. Ashfield, Andrew R. Cowley, Jonathan R. Dilworth, Paul S. Donnelly
Reaction of [Cu(MeCN)4]+ with thiosemicarbazones bearing groups such as phenol, pyridine, or ferrocene gives tetranuclear or hexanuclear clusters with functional substituents; analogous air stable fluorescent clusters can also be prepared with Ag(I).