American Chemical Society
ja109980c_si_002.cif (34.26 kB)

From Metal−Organic Squares to Porous Zeolite-like Supramolecular Assemblies

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posted on 2010-12-29, 00:00 authored by Shuang Wang, Tingting Zhao, Guanghua Li, Lukasz Wojtas, Qisheng Huo, Mohamed Eddaoudi, Yunling Liu
We report the synthesis, structure, and characterization of two novel porous zeolite-like supramolecular assemblies, ZSA-1 and ZSA-2, having zeolite gis and rho topologies, respectively. The two compounds were assembled from functional metal−organic squares (MOSs) via directional hydrogen-bonding interactions and exhibited permanent microporosity and thermal stability up to 300 °C.