cg034259f_si_002.cif (62.33 kB)

Formation of Coordination Porphyrin Pentamers in New Supramolecular Complex of Fullerene:  {(ZnTPP)4·4-TPyP}·(C60)2·(C6H5CN)3.5

Download (62.33 kB)
dataset
posted on 07.07.2004, 00:00 by Dmitri V. Konarev, Alexey L. Litvinov, Ivan S. Neretin, Natalia V. Drichko, Yury L. Slovokhotov, Rimma N. Lyubovskaya, Judith A. K. Howard, D. S. Yufit
A new supramolecular complex of fullerene C60, {(ZnTPP)4·(4-TPyP)}·(C60)2·(C6H5CN)3.5 (ZnTPP:  zinc(II) tetraphenylporphyrin; 4-TPyP:  tetra(4-pyridyl)porphyrin) involving unusual pentamers containing five porphyrin fragments, was obtained. The crystal structure, IR and UV−vis−NIR spectra of the complex, and the molecular structure of the pentamer are presented.

History