om980732o_si_001.cif (26.1 kB)

First Structurally Characterized Organometallic Chloro Oxo−Peroxo Compounds of Molybdenum and Tungsten

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posted on 11.12.1998, 00:00 by Debashis Chakraborty, Manish Bhattacharjee, Ralph Krätzner, Rolf Siefken, Herbert W. Roesky, Isabel Usón, Hans-Georg Schmidt
Reactions of H2O2 with Cp*MoCl4 and Cp*WCl4 (Cp* = C5Me5) yield chloro oxo−peroxo complexes of the type Cp*MoO(O2)Cl (1) and Cp*WO(O2)Cl (2) in high yields. The compounds have been characterized using X-ray structural analysis.