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Field-Induced Metamagnetic Transition in the FeIII−MnIII Bimetallic Chain Built by a New Cyanide-Bearing FeIII Precursor

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posted on 10.12.2007, 00:00 authored by Jae Il Kim, Houng Sik Yoo, Eui Kwan Koh, Chang Seop Hong
The use of a new precursor, mer-[Fe(mpzcq)(CN)3]- (1), produced a dimeric molecule, [Fe(mpzcq)(CN)3][Mn(salen)(H2O)]·H2O (2), and a one-dimensional zigzag chain, [Fe(mpzcq)(CN)3][Mn(salcy)]·MeOH·MeCN (3). Antiferromagnetic couplings are operating between magnetic centers through CN ligands, and a field-induced metamagnetic transition is observed in 3.