posted on 2019-03-11, 00:00authored byShangjie Tian, Jian-Feng Zhang, Chenghe Li, Tianping Ying, Shiyan Li, Xiao Zhang, Kai Liu, Hechang Lei
We
report structural properties, physical properties, and the electronic
structure of van der Waals (vdW) crystal VI3. Detailed
analysis reveals that VI3 exhibits a structural transition
from monoclinic C2/m to rhombohedral R3̅ at Ts ≈ 79 K,
similar to CrX3 (X = Cl, Br, I). Below Ts, a long-range ferromagnetic (FM) transition emerges
at Tc ≈ 50 K. The local
moment of V in VI3 is close to the high-spin state V3+ ion (S = 1). Theoretical calculations suggest
that VI3 may be a Mott insulator with a band gap of about
0.90 eV. In addition, VI3 has a relatively small interlayer
binding energy and can be exfoliated easily down to a few layers experimentally.
Therefore, VI3 is a candidate for two-dimensional FM semiconductors.
It also provides a novel platform to explore 2D magnetism and vdW
heterostructures in S = 1 system.