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End-On Azido-Bridged 3d–4f Complexes Showing Single-Molecule-Magnet Property

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posted on 19.02.2016, 04:48 authored by Xing-Cai Huang, Chun Zhou, Hai-Yan Wei, Xin-Yi Wang
Four tetranuclear 3d–4f complexes with the 4f centers bridged solely by end-on azide bridges were reported. The [CuTb]2 compound displays single-molecule-magnet behavior with hysteresis loops observed at up to 2.4 K.