ic500436g_si_001.cif (6.55 MB)

Enantioselective Inclusion of Alcohols by Solvent-Controlled Assembled Flexible Metal–Organic Frameworks

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posted on 19.05.2014, 00:00 by Lang Lin, Rongmin Yu, Xiao-Yuan Wu, Wen-Bin Yang, Jian Zhang, Xiang-Guang Guo, Zu-Jin Lin, Can-Zhong Lu
Through judicious choice of the ligands and patient regulation of the solvent conditions, three unique chiral coordination polymeric isomers have been synthesized. Their structures, gas adsorption, and structural interconversion have been studied. One of the isomers displays dynamic behavior, and its use in the enantioselective separation of chiral alcohols has also been reported.