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Electrochemical Behavior of an Aminotrithioether Ligand:  Copper(II)-Mediated Oxidative C−C Bond Formation

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posted on 12.11.2007 by Raúl Huerta, Aarón Flores-Figueroa, Víctor M. Ugalde-Saldívar, Ivan Castillo
A neutral aminotrithioether interacts with CuI, generating a coordination polymer in the solid state. Electrochemical studies indicate that the ligand is prone to oxidation by CuII, which results in a novel C−C bond formation reaction.