American Chemical Society
ja9b00171_si_002.cif (1.77 MB)

Double-Circularly Connected Saloph-Belt Macrocycles Generated from a Bis-Armed Bifunctional Monomer

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posted on 2019-04-08, 00:00 authored by Takashi Nakamura, Shinnosuke Tsukuda, Tatsuya Nabeshima
Belt-shaped macrocycles possessing saloph units as their walls have been generated by the double-circular connection of a bis-armed bifunctional monomer bearing both o-phenylenediamine and salicylaldehyde functionalities. The saloph-belt macrocycles showed unique properties, such as the selective inclusion of fullerenes (Ka(C70)/Ka(C60) > 100), utilizing their rigid scaffolds.