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Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N‑Arylation

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posted on 11.11.2015, 00:00 by Suguru Yoshida, Takahisa Yano, Yoshihiro Misawa, Yasuyuki Sugimura, Kazunobu Igawa, Shigeomi Shimizu, Katsuhiko Tomooka, Takamitsu Hosoya
A novel method for preparing a diverse range of o-sulfanylanilines is described. Direct thioamination of arynes with sulfilimines gives o-sulfanylanilines, involving C–N and C–S bond formations and migratory N-arylation.

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