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Diphenoxo-Bridged NiIILnIII Dinuclear Complexes as Platforms for Heterotrimetallic (LnIIINiII)2RuIII Systems with a High-Magnetic-Moment Ground State: Synthesis, Structure, and Magnetic Properties

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posted on 02.07.2012, 00:00 by María A. Palacios, Antonio J. Mota, José Ruiz, Mikko M. Hänninen, Reijo Sillanpää, Enrique Colacio
The first examples of pentanuclear heterotrimetallic [(LnNi)2Ru] [Ln3+ = Gd (1) and Dy (2)] complexes were prepared and magnetostructurally characterized. They exhibit ferromagnetic interactions, leading to a high-magnetic-moment ground state.