American Chemical Society
ol503000c_si_008.cif (409.01 kB)

Diastereoselective Aminooxygenation and Diamination of Alkenes with Amidines by Hypervalent Iodine(III) Reagents

Download (409.01 kB)
posted on 2014-12-05, 00:00 authored by Hui Chen, Atsushi Kaga, Shunsuke Chiba
Diastereoselective anti-aminooxygenation and anti-diamination of alkenes with amidines were enabled by hypervalent iodine­(III) reagents such as PhI­(OCOR)2 and PhI­(NMs2)2, respectively. The present transformation offers diastereochemically pure dihydroimidazoles divergently from E- and Z-alkenes.