Diastereoselective Aminooxygenation and Diamination of Alkenes with Amidines by Hypervalent Iodine(III) Reagents

dataset

posted on 2014-12-05, 00:00 authored by Hui Chen, Atsushi Kaga, Shunsuke Chiba

Diastereoselective anti-aminooxygenation and anti-diamination of alkenes with amidines were enabled by hypervalent iodine(III) reagents such as PhI(OCOR)₂ and PhI(NMs₂)₂, respectively. The present transformation offers diastereochemically pure dihydroimidazoles divergently from E- and Z-alkenes.