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Designed 4,8-Connected Metal–Organic Frameworks Based on Tetrapodal Octacarboxylate Ligands

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posted on 2011-10-05, 00:00 authored by Zu-Jin Lin, Tian-Fu Liu, Xiu-Ling Zhao, Jian Lü, Rong Cao
A flexible tetrapodal octacarboxylate ligand with four 1,3-benzenedicarboxylate units has been used to construct three polyhedral metal–organic frameworks, which show a (4,8)-connected structure of a rare scu topology comprising octahedral and cuboctahedral cages.