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Cymantrene- and Ferrocene-Based Complexes with Perfluorinated Bridging Moieties

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posted on 11.04.2011, 00:00 by Max Roemer, Peter Schmiel, Dieter Lentz
Trifluorovinylcymantrene (1) and -ferrocene (2) form the basis of a versatile building block chemistry. Di- and trinuclear complexes with perfluorinated bridging moieties are obtained by [2+2] cycloaddition on 1 and nucleophilic substitution on the C2F3 unit of 2 with cymantrenyllithium.