Cycloadditions of 1,1-Disubstituted Benzocyclobutenes Obtained by C(sp3)−H Activation
datasetposted on 20.02.2009 by Manon Chaumontet, Pascal Retailleau, Olivier Baudoin
Datasets usually provide raw data for analysis. This raw data often comes in spreadsheet form, but can be any collection of data, on which analysis can be performed.
An efficient synthesis of polycyclic molecules has been performed by a sequence involving palladium-catalyzed C−H activation and [4 + 2] cycloaddition. The intermediate benzocyclobutenes underwent a microwave-enhanced electrocyclic ring-opening/cycloaddition process with complete torquoselectivity and diastereoselectivity.