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Cyanide-Bridged WV−CoII Double-Zigzag Chain Based on an Octacoordinated W Precursor:  Metamagnetism and Spin Canting

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posted on 05.03.2007, 00:00 authored by Jung Hee Yoon, Jeong Hak Lim, Seok Woo Choi, Hyoung Chan Kim, Chang Seop Hong
A cyanide-bridged W−Co bimetallic complex (1) with a double-zigzag chain structure was characterized in terms of structure and magnetism. Compound 1 exhibits metamagnetism and spin canting induced by the presence of anisotropic CoII ions and noncovalent interactions.