American Chemical Society
ol5b03179_si_002.cif (11.81 kB)

Cu-Catalyzed Transformation of Alkynes and Alkenes with Azide and Dimethyl Sulfoxide Reagents

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posted on 2015-12-18, 00:00 authored by Tao Shen, Xiaoqiang Huang, Yu-Feng Liang, Ning Jiao
A novel and efficient Cu-catalyzed nitrogenation of alkynes and alkenes for the direct synthesis of sulfur-containing triazoles is described. Simple and readily available sulfoxides and azides are employed as the S- and N-source to prepare highly value N-,S-containing compounds from simple alkynes and alkenes.