ic035080x_si_002.cif (51.62 kB)
Download fileCopper Hydroperoxo Species Activated by Hydrogen-Bonding Interaction with Its Distal Oxygen
dataset
posted on 2003-11-03, 00:00 authored by Syuhei Yamaguchi, Shigenori Nagatomo, Teizo Kitagawa, Yasuhiro Funahashi, Tomohiro Ozawa, Koichiro Jitsukawa, Hideki MasudaA novel copper(II)−OOH complex with functional ligand that can
form a hydrogen bond with the distal oxygen of hydroperoxide
has been designed and prepared as a structural/functional model
of dopamine β-hydroxylases, whose spectroscopic characterization
and decomposition rates have indicated that the hydroperoxide is
activated through the hydrogen-bonding interaction with the distal
oxygen.
