ja0c12064_si_005.cif (4.69 MB)

Controlled Self-Assembly and Multistimuli-Responsive Interconversions of Three Conjoined Twin-Cages

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posted on 20.01.2021, 23:29 by Li-Xuan Cai, Dan-Ni Yan, Pei-Ming Cheng, Jin-Jin Xuan, Shao-Chuan Li, Li-Peng Zhou, Chong-Bin Tian, Qing-Fu Sun
Stimuli-responsive structural transformations between discrete coordination supramolecular architectures not only are essential to construct smart functional materials but also provide a versatile molecular-level platform to mimic the biological transformation process. We report here the controlled self-assembly of three topologically unprecedented conjoined twin-cages, i.e., one stapled interlocked Pd12L6 cage (2) and two helically isomeric Pd6L3 cages (3 and 4) made from the same cis-blocked palladium corners and a new bis-bidentate ligand (1). While cage 2 features three mechanically coupled cavities, cages 3 and 4 are topologically isomeric helicate-based twin-cages based on the same metal/ligand stoichiometry. Sole formation of cage 2 or a dynamic mixture of cages 3 and 4 can be controlled by changing the solvents employed during the self-assembly. Structural conversions between cages 3 and 4 can be triggered by changes in both temperature/solvent and induced-fit guest encapsulations. Well-controlled interconversion between such topologically complex superstructures may lay a solid foundation for achieving a variety of functions within a switchable system.