American Chemical Society
ja049849w_si_002.cif (11.97 kB)

Catalytic, Highly Enantio, and Diastereoselective Nitroso Diels−Alder Reaction

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posted on 2004-04-07, 00:00 authored by Yuhei Yamamoto, Hisashi Yamamoto
This communication presents studies that nitroso Diels−Alder adduct has been furnished in uniformly high yield and high enantioselectivity using nitrosopyridine as a substrate and copper as a catalyst. The obtained Diels−Alder adduct was easily transformed to corresponding chiral amino alcohols without loss of enantioselectivity.