American Chemical Society
ja105945z_si_002.cif (36.01 kB)

Catalytic Asymmetric Protonation of α-Amino Acid-Derived Ketene Disilyl Acetals Using P-Spiro Diaminodioxaphosphonium Barfates as Chiral Proton

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posted on 2010-09-08, 00:00 authored by Daisuke Uraguchi, Natsuko Kinoshita, Takashi Ooi
Chiral diaminodioxaphosphonium salts have been developed and their unique abilities as a chiral proton have been revealed through the establishment of a highly enantioselective protonation of α-amino acid-derived ketene disilyl acetals.