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Catalytic Asymmetric Intermolecular Bromoesterification of Unfunctionalized Olefins

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posted on 2014-07-18, 00:00 authored by Lijun Li, Cunxiang Su, Xiaoqin Liu, Hua Tian, Yian Shi
An asymmetric intermolecular bromoesterification of unfunctionalized olefins catalyzed by (DHQD)2PHAL is described. Optically active bromoesters can be obtained with up to 92% ee.

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    OpticallybromoesterDHQDunfunctionalized olefinsUnfunctionalized OlefinsAnbromoesterificationCatalytic Asymmetric Intermolecular Bromoesterificationee

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