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Cage Hydrocarbons Derived from Dibenzosuberenone

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posted on 06.11.2009, 00:00 by Marcus Pillekamp, Wasim Alachraf, Iris M. Oppel, Gerald Dyker
The reinvestigation of the synthesis of the fascinating cage compound 2 reveals an incorrect structure of photodimer 2, as well as of the putatively isolated intermediate 9. These products have to be reassigned as monomeric pyramidalized alkene 3 and spirocyclic dichloride 10, respectively.

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