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Boraphosphaalkene Synthesis via Phosphaalkyne Insertion into 9‑Borafluorene

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posted on 16.05.2018, 19:37 by Sam Yruegas, Jonathan H. Barnard, Khalidah Al-Furaiji, Jason L. Dutton, David J. D. Wilson, Caleb D. Martin
The reaction of 1-adamantylphosphaalkyne with 9-phenyl-9-borafluorene resulted in the insertion of the PC unit into the endocyclic B–C bond, generating a seven-membered 1,3-boraphosphaalkene. The mechanism was investigated computationally, indicating that the reaction proceeds via a bond metathesis pathway.

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