om8b00248_si_005.xyz (2.85 kB)
Download fileBoraphosphaalkene Synthesis via Phosphaalkyne Insertion into 9‑Borafluorene
dataset
posted on 2018-05-16, 19:37 authored by Sam Yruegas, Jonathan H. Barnard, Khalidah Al-Furaiji, Jason L. Dutton, David J. D. Wilson, Caleb D. MartinThe reaction of 1-adamantylphosphaalkyne
with 9-phenyl-9-borafluorene
resulted in the insertion of the PC unit into the endocyclic
B–C bond, generating a seven-membered 1,3-boraphosphaalkene.
The mechanism was investigated computationally, indicating that the
reaction proceeds via a bond metathesis pathway.
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