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Bis(dipyrrinato)zinc(II) Complexes: Emission in the Solid State

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posted on 07.06.2016, 11:49 authored by Mizuho Tsuchiya, Ryota Sakamoto, Masaki Shimada, Yoshinori Yamanoi, Yohei Hattori, Kunihisa Sugimoto, Eiji Nishibori, Hiroshi Nishihara
This Communication reports the first observation of solid-state photoluminescence in bis­(dipyrrinato)­zinc­(II) complexes with various substituents. The report discusses the effect of their substituents on their crystal structures and spectroscopic properties. Their meso-aryl groups are revealed to play important roles in the spectroscopic properties in the solid state.