posted on 2019-01-28, 19:03authored byLars Süsse, James H. W. LaFortune, Douglas W. Stephan, Martin Oestreich
Axially chiral [(C6F5)3PF][B(C6F5)4] analogues based on dihydrophosphepines
with a binaphthyl backbone were prepared and structurally characterized
by X-ray diffraction analysis. Computational calculations of FIA and
GEI values attest that these new fluorophosphonium cations have a
higher Lewis acidity compared to the ubiquitous B(C6F5)3. Furthermore, application of these highly electrophilic
compounds in the catalytic hydrosilylation of ketones and an investigation
of the mechanism lead to a refined picture of the role of highly electrophilic
fluorophosphonium cations.