ol4010646_si_002.cif (23.46 kB)
Download fileAsymmetric Synthesis of Indole Homo-Michael Adducts via Dynamic Kinetic Friedel–Crafts Alkylation with Cyclopropanes
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posted on 2013-05-17, 00:00 authored by Steven M. Wales, Morgan M. Walker, Jeffrey S. JohnsonAn enantioconvergent Friedel–Crafts alkylation of indoles with donor–acceptor cyclopropanes is described. The reaction is catalyzed by pybox•MgI2 and proceeds via a type I dynamic kinetic asymmetric transformation (DyKAT).
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