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Asymmetric Construction of a Ferrocenyl Phosphapalladacycle from Achiral Enones and a Demonstration of Its Catalytic Potential

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posted on 13.10.2014, 00:00 authored by Kennard Gan, Abdul Sadeer, Chang Xu, Yongxin Li, Sumod A. Pullarkat
A new approach toward ferrocenyl phosphapalladacycle construction from achiral enones via asymmetric hydrophosphination and subsequent diastereoselective C–H activation is described. Its catalytic efficacy toward C–C bond formation is subsequently illustrated.