om6b00333_si_002.cif (503.8 kB)
Aryl and Benzyl C–H Activation of N‑Substituted PNP Ligands
dataset
posted on 2016-06-14, 18:20 authored by Sean P. Vilanova, Vlad M. IlucThe synthesis of the N-aryl-substituted PNP pro-ligands
H(PNnaphP) (N-di(2-diisopropylphosphine-4-methylphenyl)naphthylamine)
and H(PNtolP) (N-di(2-diisopropylphosphine-4-methylphenyl)-o-tolylamine) is reported. The corresponding iridium(III)
complexes, [(PNnaphP)Ir(H)Cl], [(o-methyl-PNtolP)Ir(H)Cl], [(o-aryl-PNtolP)Ir(H)Cl], [(PNnaphP)Ir(H)2], [(o-methyl-PNtolP)Ir(H)2], and
[(o-aryl-PNtolP)Ir(H)2], were also synthesized and structurally characterized, along with
reaction intermediates, demonstrating various ligand coordination
modes.