ja4031243_si_003.cif (122.37 kB)

Anion-Dependent Self-Assembly of Near-Infrared Luminescent 24- and 32-Metal Cd–Ln Complexes with Drum-like Architectures

Download (122.37 kB)
posted on 12.06.2013, 00:00 by Xiaoping Yang, Desmond Schipper, Richard A. Jones, Lauren A. Lytwak, Bradley J. Holliday, Shaoming Huang
Two series of 4d–4f clusters [Ln8Cd24L12­(OAc)48] and [Ln6Cd18L9Cl8(10)­(OAc)28(26)] (Ln = Nd, Gd, Er, and Yb) with novel drum-like structures were prepared using a flexible Schiff base ligand. Their NIR luminescence properties were determined.