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Anion-Dependent Self-Assembly of Near-Infrared Luminescent 24- and 32-Metal Cd–Ln Complexes with Drum-like Architectures

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posted on 2013-06-12, 00:00 authored by Xiaoping Yang, Desmond Schipper, Richard A. Jones, Lauren A. Lytwak, Bradley J. Holliday, Shaoming Huang
Two series of 4d–4f clusters [Ln<sub>8</sub>Cd<sub>24</sub>L<sub>12</sub>­(OAc)<sub>48</sub>] and [Ln<sub>6</sub>Cd<sub>18</sub>L<sub>9</sub>Cl<sub>8(10)</sub>­(OAc)<sub>28(26)</sub>] (Ln = Nd, Gd, Er, and Yb) with novel drum-like structures were prepared using a flexible Schiff base ligand. Their NIR luminescence properties were determined.

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