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An Unusual Three-Dimensional Coordination Network Formed by Parallel Polycatenation of Two-Fold Interpenetrated (6,3) Layers Based on a Novel Three-Connecting Ligand

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posted on 07.01.2004, 00:00 authored by Stefano Banfi, Lucia Carlucci, Enrico Caruso, Gianfranco Ciani, Davide M. Proserpio
The novel tridentate ligand 1,3,5-tris(4-cyano-phenoxymethyl)-2,4,6-trimethylbenzene (1) together with silver(I) triflate has afforded the interesting coordination polymer [Ag(1)(CF3SO3)]·0.5H2O, containing undulated (6,3) layers of hexagonal meshes, with alternating Ag and 1 triconnected centers, entangled into 2-fold parallely interpenetrated sheets, which, furthermore, are polycatenated to generate an unique three-dimensional array.