American Chemical Society
om7012343_si_001.cif (25.56 kB)

An Organocadmium Hydroxylamide

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Version 2 2016-06-03, 23:45
Version 1 2016-02-27, 16:48
posted on 2008-03-24, 00:00 authored by Surajit Jana, Roland Fröhlich, Alexander Hepp, Norbert W. Mitzel
The first organometallic cadmium hydroxylamide [Cd(MeCd)4(ONEt2)6] (1) has been prepared by alkane elimination from dimethylcadmium upon treatment with N,N-diethylhydroxylamine and characterized by variable-temperature NMR spectroscopy (1H, 13C, 113Cd), single-crystal X-ray diffraction, and elemental analysis. In the solid state compound 1 comprises an Cd5N6O6 backbone with a central octahedral coordinate Cd atom, while all 12 donor atoms are attached to the 5 Cd nuclei whereas in solution it is of highly dynamic nature.