American Chemical Society
om300902t_si_002.cif (63.26 kB)

Amination of Aryl Iodides Catalyzed by a Palladium–Copper Complex Supported by a Chelate-Bridging Ligand

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posted on 2012-11-12, 00:00 authored by Naofumi Tsukada, Nozomi Ohnishi, Shiori Aono, Fusako Takahashi
Palladium–copper complexes supported by a new chelate-bridging ligand designed for a cooperative effect of two metals were synthesized. The bimetallic complexes exhibited higher activities as catalysts for amination of aryl iodides than mononuclear catalyst.