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A Two-Dimensional Metal-Organic Framework Based on a Ferromagnetic Pentanuclear Copper(II)

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posted on 01.02.2010, 00:00 authored by Xia Zhu, Jun-Wei Zhao, Bao-Long Li, You Song, Yu-Mei Zhang, Yong Zhang
The hydrothermal reaction of CuSO4, 1,2-benzenedicarboxylate (phth), and 1,2-bis(imidazol-1-yl)ethane (bime) yields the two-dimensional metal-organic framework {[Cu5(bime)(μ3-OH)2(phth)4](H2O)2}n (1), which is based on the pentanuclear copper(II) cluster [Cu53-OH)2(phth)4] and shows dominant ferromagnetic interactions within the pentanuclear cluster.

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