ic6b01203_si_002.cif (3.73 MB)
Download file

A Selenium-Containing Diarylamido Pincer Ligand: Synthesis and Coordination Chemistry with Group 10 Metals

Download (3.73 MB)
dataset
posted on 09.06.2016, 11:49 by Bronte J. Charette, Jamie S. Ritch
The synthesis of new bifunctional organoselenium diarylamine compounds RN­(4-Me-2-SeMe-C6H3)2 (R = Me: 1; R = tert-butoxycarbonyl (Boc): 2; R = H: 3-H) via aryllithium chemistry is disclosed. Compound 1 serves as a Se,Se-bidentate neutral ligand toward PdII, forming the coordination complex {PdCl2[MeN­(4-Me-2-SeMe-C6H3)22Se)]} (1-Pd) in reaction with [PdCl2(COD)] (COD = 1,5-cyclooctadiene), while the protio ligand 3-H forms tridentate pincer complexes [MCl­(N­(4-Me-2-SeMe-C6H3)2)] (M = Pd: 3-Pd; M = Pt: 3-Pt) with [MCl2(COD)] (M = Pd, Pt) in the presence of triethylamine. Complex 1-Pd does not undergo N–C cleavage at high temperature, unlike related alkylphosphine-bearing complexes. All compounds have been characterized by multinuclear (1H, 13C, 77Se) NMR spectroscopy, and crystal structures of 1, 1-Pd, 3-Pd, and 3-Pt are reported. Additionally, density functional theory calculations have been performed on the pincer complexes to contrast them with well-known analogues containing phosphine donor groups.

History