ja504020t_si_003.cif (34.16 kB)
A Nitrido Salt Reagent of Titanium
dataset
posted on 2014-06-11, 00:00 authored by Rick Thompson, Chun-Hsing Chen, Maren Pink, Gang Wu, Daniel J. MindiolaDeprotonation of
the parent titanium imido (tBunacnac)TiNH(Ntolyl2) (tBunacnac– = [ArNCtBu]2CH; Ar = 2,6-iPr2C6H3) with KCH2Ph forms a rare example of a molecular
titanium nitride as a dimer, {[K][(tBunacnac)TiN(Ntolyl2)]}2. From the parent imido or nitride salt, the
corresponding aluminylimido–etherate adduct, (tBunacnac)TiN[AlMe2(OEt2)](Ntolyl2), can be isolated and structurally characterized. The parent
imido is also a source for the related borylimido, (tBunacnac)TiNBEt2(Ntolyl2).