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A New Rhodium(III) Complex with a Tripodal Bis(imidazolylidene) Ligand. Synthesis and Catalytic Properties

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posted on 02.02.2004, 00:00 by Elena Mas-Marzá, Macarena Poyatos, Mercedes Sanaú, Eduardo Peris
A new bis(imidazolylidene) tripodal ligand has been obtained by a simple method. The coordination of this ligand to Rh provides the first Rh(III) complex with a bis(carbene) ligand in a tripodal coordination, and its catalytic properties toward hydrogen transfer have been examined.