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A New Redox-Active Coordination Polymer with Cobalticinium Dicarboxylate

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posted on 20.09.2004, 00:00 by Mitsuru Kondo, Yuri Hayakawa, Makoto Miyazawa, Aiko Oyama, Kei Unoura, Hiroyuki Kawaguchi, Tetsuyoshi Naito, Kenji Maeda, Fumio Uchida
A new two-dimensional coordination polymer with cobalticinium 1,1‘-dicarboxylate (ccdc) incorporated in the framework has been prepared, the ccdc functioning as unique monoanionic dicarboxylate ligands. The compound shows a high redox activity based on the ccdc units.