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A Highly Porous Interpenetrated Metal–Organic Framework from the Use of a Novel Nanosized Organic Linker

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posted on 22.02.2016, 14:21 authored by Manolis J. Manos, Marios S. Markoulides, Christos D. Malliakas, Giannis S. Papaefstathiou, Nikos Chronakis, Mercouri G. Kanatzidis, Pantelis N. Trikalitis, Anastasios J. Tasiopoulos
The initial use of a novel elongated tricarboxylic acid H3hmpib in metal–organic framework (MOF) chemistry resulted in a [Zn4O­(hmpib)2] MOF (UCY-1) with pyrite topology. The compound displays a remarkably high internal surface area despite its double-interpenetrated structure as well as high CO2 uptake and selective adsorption for it over CH4.