ja400506j_si_006.cif (14.46 kB)
A Catalytic Enantioselective Tandem Allylation Strategy for Rapid Terpene Construction: Application to the Synthesis of Pumilaside Aglycon
dataset
posted on 2013-02-20, 00:00 authored by Grace
E. Ferris, Kai Hong, Ian A. Roundtree, James P. MorkenCatalytic enantioselective 1,2-diboration of 1,3-dienes
followed
by cascade allylborations with dicarbonyls provides rapid entry into
carbocyclic reaction products. The stereochemical course of this reaction
was studied along with its application in the synthesis of pumilaside aglycon.