American Chemical Society
ic801247t_si_009.cif (23.31 kB)

1,2,4-Diazaphospholide Complexes of Samarium(III)

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posted on 2008-11-03, 00:00 authored by Chengfu Pi, Li Wan, Yingying Gu, Wenjun Zheng, Linhong Weng, Zhenxia Chen, Limin Wu
A series of 1,2,4-diazaphospholide (dp) samarium complexes with a variety of coordination modes were prepared via the metathesis reaction of SmCl3(THF)3 and potassium 3,5-disubstituted 1,2,4-diazaphospholide or by the reaction of Sm[N(SiMe3)2]3 and 3,5-diphenyl-1,2,4-diazaphosphole.