ol500963p_si_001.pdf (1.61 MB)
N‑Arylations of Sulfoximines with 2‑Arylpyridines by Copper-Mediated Dual N–H/C–H Activation
journal contribution
posted on 2014-05-16, 00:00 authored by Long Wang, Daniel L. Priebbenow, Wanrong Dong, Carsten BolmA high-yielding method providing
rapid access to new N-arylated sulfoximines has been
developed. A stoichiometric amount
of copper facilitates the C–H activation of 2-arylpyridines
which then undergo oxidative C–N cross-couplings with various
sulfoximine derivatives.