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[Bu4P]+Cl-Catalyzed Reactions of Trichlorosilane and Dichloromethylsilane with Vinyltrichlorosilane: New Synthetic Method for 1,1,4,4-Tetrachloro-2,5-bis(trichlorosilyl)-1,4-disilacyclohexane Compounds

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posted on 2010-07-12, 00:00 authored by Soon Hyun Hong, Sang Il Hyun, Il Nam Jung, Won-Sik Han, Min-Hye Kim, Hoseop Yun, Suk-Woo Nam, Sang Ook Kang
[Bu4P]+Cl-catalyzed reactions of trichlorosilane and dichloromethylsilane with vinyltrichlorosilane gave 1,1,4,4-tetrachloro-2,5-bis(trichlorosilyl)-1,4-disilacyclohexane (1) and 1,1,4,4-tetrachloro-2,5-bis(methyldichlorosilyl)-1,4-disilacyclohexane (4), respectively.

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