[3]Rotaxane-Based Dinuclear Palladium Catalysts for Ring-closure Mizoroki–Heck Reaction

Suzaki, Yuji; Shimada, Kyoichi; Chihara, Eriko; Saito, Takashi; Tsuchido, Yoshitaka; Osakada, Kohtaro

doi:10.1021/ol201357b.s001

ol201357b_si_001.pdf (172.56 kB)

[3]Rotaxane-Based Dinuclear Palladium Catalysts for Ring-closure Mizoroki–Heck Reaction

journal contribution

posted on 2011-08-05, 00:00 authored by Yuji Suzaki, Kyoichi Shimada, Eriko Chihara, Takashi Saito, Yoshitaka Tsuchido, Kohtaro Osakada

[3]Rotaxane containing two Pd centers in the cyclic compounds catalyzes a Mizoroki–Heck reaction of substrates with two iodophenyl groups with bisacrylate. Formation of the cyclic products is enhanced by the rotaxane catalyst more smoothly than Pd(OAc)₂.