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ZnGaNO Photocatalyst Particles Prepared from Methane-Based Nitridation Using Zn/Ga/CO3 LDH as Precursor
journal contribution
posted on 2018-07-20, 00:00 authored by Yan-Ling Hu, Shuhua Ou, Jialiang Huang, Huayu Ji, Siwan Xiang, Yuqin Zhu, Zhibang Chen, Cheng Gong, Lan Sun, Jiqiong Lian, Dongya Sun, Yongsheng Fu, Tongmei MaMethane-based
nitridation was employed to produce wurtzite zinc-gallium oxynitride
(ZnGaNO) photocatalyst particles using Zn/Ga/CO3 layered
double hydroxides (LDHs) as precursor. Introduction of methane to
nitridation would promote the formation of Zn–O bonding and
suppress shallow acceptor complexes such as V(Zn)-Ga(Zn) and Ga-Oi in ZnGaNO particles. On the other
hand, high flow rate of methane would induce breaking of Ga–N
bonding and enhance surface deposition of metallic Ga atoms. After
loading with Rh and RuO2, ZnGaNO particles had free electron
density in an order of S50 > S20 > S90 > S0, which correlated
well with their photocatalytic performance upon visible-light irradiation.
The best performance of the loaded S50 was ascribed to the relatively
flat surface band bending of the particle. Methane-based nitridation
of Zn/Ga/CO3 LDHs would provide a new route to tune the
surface chemistry of ZnGaNO and enhance the photocatalytic performance
to its full potential.